Journal Information
Vol. 8. Issue 1.
Pages 795-803 (January - March 2019)
Download PDF
More article options
Vol. 8. Issue 1.
Pages 795-803 (January - March 2019)
Original Article
DOI: 10.1016/j.jmrt.2018.06.010
Open Access
Phase prediction, microstructure and high hardness of novel light-weight high entropy alloys
Jon Mikel Sancheza,
Corresponding author

Corresponding author.
, Iban Vicarioa, Joseba Albizurib, Teresa Gurayac, Jose Carlos Garciaa
a Department of Foundry and Steel making, Tecnalia Research & Innovation, Derio, Spain
b Department of Mechanical Engineering, Faculty of Engineering of Bilbao (UPV/EHU), Bilbao, Spain
c Department of Mining & Metallurgical Engineering and Materials Science, Faculty of Engineering of Bilbao (UPV/EHU), Bilbao, Spain
This item has received

Under a Creative Commons license
Article information
Full Text
Download PDF
Figures (8)
Show moreShow less
Tables (4)
Table 1. Phases predicted, phase constitution and amount of phase (mol %) of Al40Cu15Fe10Cr15Fe15Si15 (HEA1), Al65Cu5Cr5Si15Mn5Ti5 (HEA2) and Al60Cu10Fe10Cr5Mn5Ni5Mg5 (HEA3) cast alloys, using of Thermo-Calc software with TCAL5 database.
Table 2. List of phases, volume fraction (mol %), Space Group and the lattice parameters of Al40Cu15Fe10Cr15Fe15Si15 (HEA1), Al65Cu5Cr5Si15Mn5Ti5 (HEA2) and Al60Cu10Fe10Cr5Mn5Ni5Mg5 (HEA3) cast alloys obtained by XRD.
Table 3. Chemical composition in at. % of the manufactured alloys.
Table 4. Density and microhardness of manufactured alloys in comparison with other published results.
Show moreShow less

Guided by CALPHAD modeling, low-density and multiphase three novel High Entropy Alloys (HEAs), Al40Cu15Cr15Fe15Si15, Al65Cu5Cr5Si15Mn5Ti5 and Al60Cu10Fe10Cr5Mn5Ni5Mg5 were produced by large scale vacuum die casting. A mixture of simple and complex phases was observed in the as-cast microstructures, which demonstrates good agreement with CALPHAD results. The measured densities varied from 3.7g/cm3 to 4.6g/cm3 and microhardness from 743Hv to 916Hv. Finally, the hardness of all the light-weight HEAs (LWHEAs) with densities below 4.6g/cm3 manufactured to date were reviewed. The hardness of Al40Cu15Cr15Fe15Si15 and hardness to density ratio of Al65Cu5Cr5Si15Mn5Ti5 are the highest of all LWHEAs reported up to date.

High entropy alloys
High hardness
Phase composition
Complex Concentrated Alloys
Full Text

HEAs have become a new research focus in the materials community in the last 14 years. The number of publications on this topic has grown enormously since the first publications in 2004 [1,2]. HEAs contains several major elements without a clear base element in contrast to conventional metallic alloys. The idea behind this new concept is that it is possible to stabilize a single phase solid solution (SS) by reducing Gibbs free energy, avoiding the formation of fragile intermetallic compounds (IC). Thus, the alloys are composed of five or more metallic elements in equimolar or nearly equimolar concentrations. HEAs have much higher mixing entropy values than traditional alloys in the liquid state or in the random SS state. Usually four “core effects” are used to describe the exceptional properties of HEAs: high entropy, sluggish diffusion, severe lattice distortion and cocktail effect [3]. Recently, a certain attention has been shifted to the study of multiphase HEAs with non-equiatomic compositions due to their excellent properties [4–11]. Multiphase HEAs are mainly composed of two phases, which are known as Complex Concentrated Alloys (CCAs). The term HEAs remained for the sake of simplicity and will be used throughout the present work. The vast range of complex compositions, microstructures and the properties of these novel alloys were reviewed by Miracle et al. [12] and Zhang et al. [13].

Considering that the total number of possible HEAs is around 10177[14], the implementation of an efficient method for predicting phase formation in HEAs is critical for the development of new engineering materials. Three types of methodologies have been developed for predicting phase formation in HEAs. At the beginning, various empirical thermo-physical parameters were proposed following the Hume–Rothery rules [15–18]. Gao et al. reviewed these parameters concluding that they are efficient in separating single-phase SS from amorphous alloys, but they fail to separate single-phase SS from multiphase microstructures [19]. More recently, the first-principles density functional theory (DFT) calculations combined with hybrid Monte Carlo/Molecular Dynamics (MC/MD) simulations have been applied to HEAs with reasonably success [20,21]. To date, the CALPHAD method can be regarded as the most robust method for HEAs design [22]. This method can accelerate the development of new HEAs through phase diagrams and phase stabilities calculated from multicomponent thermodynamic databases [23]. Most thermodynamic databases have been developed for specific commercial alloys, which mean that they usually have optimal compositional ranges of application. But HEAs are not based on a main element like traditional alloys. Therefore, some specific databases were developed for phase prediction in HEAs. This databases are TCHEA [24,25] and PanHEA [19,26] supplied by Thermo-CalcTM and PandatTM respectively, but they are mainly restricted to transition metals containing HEAs. Thus, the latest version of TCHEA has been developed in a 26 element framework assessed to their full range of composition [27]. On the other hand, PanHEA database is actually restricted to 10 elements [28]. In some cases, the use of standard databases for commercial alloys such as TCAL and TCNI has shown acceptable efficacy in predicting phase stability of HEAs [29,30].

LWHEAs have recently attracted more attention for their excellent mechanical properties [31–35] and the possibility of reducing the weight in the transport or energy industry. In this work, only HEAs with a density equal to or less than commercial Ti alloys were defined as LWHEAs. Ti alloys are the heaviest of the light alloys used in engineering to reduce the weight of structures and components [36]. The pioneering LWHEA was nanocrystalline Al20Li20Mg10Sc20Ti30 alloy, high hardness (591Hv) and low density (2.7g/cm3) were reported by Youssef et al. [37]. To date, the hardness and hardness to density ratio of Al20Be20Fe10Si15Ti35 alloy are the highest reported before [38]. The estimated strength of this alloy is 2976MPa, which is superior to those of traditional light-weight structural materials. Therefore, LWHEAs can be used as protective coating of machine components and tools because of their high hardness and excellent wear resistance [39].

Motivated by the above concerns, low-density and affordable Al40Cu15Cr15Fe15Si15, Al65Cu5Cr5Si15Mn5Ti5 and Al60Cu10Fe10Cr5Mn5Ni5Mg5 alloys were designed by CALPHAD method with the objective of achieving multiphase microstructure to exceed the hardness, wear behavior, and the performance of low-density alloys in high-temperature applications. The major driver of the alloy design was to reduce the density through increasing the molar % of Al, obtaining Al-based non-equimolar HEAs. This has allowed the good liquidity and castability of the molten alloys. Furthermore, the addition of Cr was critically necessary for the formation of high-temperature phases, while additions of Mn, Ni, Cu, Si and Fe enhanced solid solution strengthening. To reduce the alloy cost, expensive or scarce elements were avoided.

2Experimental procedures

Thermo-Calc software (v. 2017b, Thermo-Calc Software AB, Stockholm, Sweden) [40] in conjunction with thermodynamic database TCAL5 was used for the equilibrium phases as a function of temperature calculation.

The raw elements with a minimum purity of 99.5wt. % were melted and merged in an alumina crucible in an electric vacuum induction furnace model VIM (CONSARC, Rancocas, USA). Due to the high melting point of chromium, tablets of Al-Cr containing 75wt. % of Cr were used. Before melting, a minimum chamber vacuum of 0.071mbar was achieved and a protective Ar gas atmosphere was introduced to prevent oxidation reactions during melting, with a chamber pressure of 400mbar. The molten alloy was poured and solidified into a metal die inside the furnace for at least 4h.

Specimens of approximately 80mm (length)×80mm (width)×140mm (thickness) were obtained from the as-cast material. The samples of each alloy were cut from the ingots and prepared according to standard metallographic procedures by hot mounting in conductive resin, grinding, and polishing.

The X-ray diffraction (XRD) equipment used to characterize the crystal structures of the alloys was a model D8 ADVANCE (BRUKER, Karlsruhe, Germany), with Cu Kα radiation, operated at 40kV and 30mA. The diffraction diagrams were measured at the diffraction angle 2θ, range from 10° to 90° with a step size of 0.01°, and 1.8s/step. The powder diffraction file (PDF) database 2008 was applied for phase identification.

The microstructure, the different regions and the averaged overall chemical composition of each sample were investigated using a scanning electron microscope (SEM), equipped with an energy dispersive X-ray spectrometry (EDS) model JSM-5910LV (JEOL, Croissy-sur-Seine, France).

Vickers microhardness FM-700 model (FUTURE-TECH, Kawasaki, Japan) was performed on the polished sample surface using a 0.1kg load, applied for 10s. At least 10 random individual measurements were made. Finally, density measurement was conducted using the Archimedes method.

3Results and discussion

The thermodynamic calculations of equilibrium phases in manufactured alloys as a function of temperature were calculated using Thermo-Calc software and TCAL5 database as shown in Fig. 1. TCAL5 database is commonly used for Al commercial alloys. But according to previous works [30,31], the use of this database in Al-based HEAs shows good agreement with the experimental results. Regarding the very low cooling rate used in the present study, it is reasonable to assume that the alloys are close to thermodynamic equilibrium. Nevertheless, it should be noted that calculations were made for homogeneous alloys and not considering impurities from the Al-Cr tablets or oxides formed during the casting process.

Fig. 1.

Calculated phase diagrams of the manufactured alloys (a) Al40Cu15Cr15Fe15Si15, (b) Al65Cu5Cr5Si15Mn5Ti5 and (c) Al60Cu10Fe10Cr5Mn5Ni5Mg5; using Thermo-Calc software with TCAL5 database.


Fig. 1(a) shows that no major change is expected below 246°C in Al40Cu15Cr15Fe15Si15 cast alloy, which is the temperature of precipitation of the AlFeSi (τ1) phase. The τ1 phase is predicted to slightly grow at the expense of BCC (B2) phase. The simulation suggested the formation of five phases at room temperature (RT), but the amount of Al3Zr5 (D8m) is insignificant. The solidus temperature is 800°C. In Fig. 1(b), five phases were predicted in equilibrium at RT for Al65Cu5Cr5Si15Mn5Ti5 cast alloy. All the phases are stable below 429°C, and the solidus temperature is 534°C. According to the Thermo-Calc equilibrium phase diagram of Al60Cu10Fe10Cr5Mn5Ni5Mg5 cast alloy in Fig. 1(c), some qualitative and quantitative changes are expected below 326°C in Al8Mn5 and τ1-AlFeSi phase. The solidus temperature is 506°C. The whole quantity of these minor phases only represents 10mol % of the amount of phase at RT. The diagrams suggest high phase stability of the designed alloys at high temperatures.

In Table 1, the thermodynamic calculations of equilibrium phases were summarized with the detailed description of their phase constitution and the amount of phase. The phase constitution obtained by TCAL5 database reflects that multiple elements can be dissolved in the sublattices. The amount of each element calculated for each sublattice has been neglected, this analysis has only been considered in a qualitative and not a quantitative way. Although the alloys are close to thermodynamic equilibrium, they are not expected to be in complete equilibrium. In addition, is supposed that the above mentioned high entropy, sluggish diffusion and severe lattice distortion effects can enrich the solution of the elements in each phase.

Table 1.

Phases predicted, phase constitution and amount of phase (mol %) of Al40Cu15Fe10Cr15Fe15Si15 (HEA1), Al65Cu5Cr5Si15Mn5Ti5 (HEA2) and Al60Cu10Fe10Cr5Mn5Ni5Mg5 (HEA3) cast alloys, using of Thermo-Calc software with TCAL5 database.

Alloy  Phase  Phase constitution  Mol % 
HEA1Al10Cu10Fe  (Fe)1 (Al,Cu)10 (Al)10  16 
Al13Fe4  (Al,Cu)0.63 (Fe)0.23 (Al,Si,VA)0.14  43 
Al3Zr5 (D8m)  (Al,Si)3 (Cr)5 
AlFeSi (τ1(Al,Si)5 (Fe)3 
FeSi (B20)  (Cr,Fe)1 (Al,Si)1  33 
HEA2Al13Cr4Si4  (Al)13 (Cr)4 (Si)4  20 
Al15Si2Mn4  (Al)16 (Mn)4 (Si)1 (Al,Si)2  40 
Al2Cu (C16)  (Al,Mn)2 (Al,Cu,Mn,Si)1  18 
Al5Si12Ti7  (Al,Si)0.21 (Si)0.5 (Ti)0.29  11 
FCC (L12(Al,Cr,Cu,Mn,Si,Ti)0.75(Al,Cr,Cu,Mn,Si,Ti)0.25 (VA)1  11 
HEA3Al13Fe4  (Al,Cu)0.63 (Fe,Mn,Ni)0.23 (Al,VA)0.14  33 
Al3Ni2  (Al)3 (Al,Cu,Fe,Mg,Ni)2 (Ni,VA)1 
Al7Cu4Ni  (Al)1 (Cu,Fe,Ni,VA)1  35 
Al8Mn5  (Al)12 (Mn)5 (Al,Cu,Mn)9 
ϒ (D810(Al)12 (Cr)5 (Al,Cr)9  16 
τ-phase  (Mg)26 (Al,Mg)6 (Al,Cu,Mg)48 (Al)1 

According to Thermo-Calc simulations, a multiphase character can be expected for the manufactured alloys, which is proven by the results of XRD measurements shown in Fig. 2. Considering that the intensities of the diffraction peaks of ordered phases are stronger than those of SS phases, the volume fractions of non-stoichiometric compounds appear to predominate.

Fig. 2.

XRD diffraction patterns of the cast (a) Al40Cu15Fe10Cr15Fe15Si15, (b) Al65Cu5Cr5Si15Mn5Ti5 and (c) Al60Cu10Fe10Cr5Mn5Ni5Mg5.


Fig. 2(a) shows the XRD patterns of the as-cast Al40Cu15Cr15Fe15Si15 alloy. The XRD peaks of the alloy corresponds to Al13Fe4, Fe3Al2Si31) and FeSi phases. All phases present low diffraction peaks, except Al13Fe4 phase at 22° and 24°. Thus, all the phases predicted by Thermo-Calc were observed in XRD diagram, with the exception of Al10Cu10Fe andAl3Zr5 (D8m) phase. Fig. 2(b) shows the XRD pattern of the as-cast Al65Cu5Cr5Si15Mn5Ti5 alloy. All the phases in equilibrium predicted by Thermo-Calc were observed, except Al13Cr4Si4 phase. These phases were indexed as Al13Cr4Si4, Al0.74Mn0.20Si0.06, Al2Cu, Al5Si12Ti7 and Al19Mn4. FCC (L12) and Al15Si2Mn4 phases predicted by Thermo-Calc corresponds to Al19Mn4 and Al0.74Mn0.20Si0.06 respectively. The corresponding XRD pattern of the as-cast Al60Cu10Fe10Cr5Mn5Ni5Mg5 alloy is shown in Fig. 2(c). Strong diffraction peak is observed at 44°, corresponding to Al3Ni2 and Al7Cu4Ni phases. The last phase was indexed as cubic Mg2Cu6Al5 phase, which was correlated to Mg2Cu6Al5. The volume fractions of constitutive phases were calculated experimentally by XRD and detailed in Table 2. In HEA1, the experimental volume fraction of the phases is consistent with thermodynamic calculations of FeSi and τ1-AlFeSi phases in Table 1. But the phase volume of Al13Fe4 calculated by XRD is quite higher. In HEA2, the predicted volume of phase and the experimental result obtained by XRD are in good accordance. In HEA3, fewer phases than those calculated by Thermo-Calc were observed in the XRD patterns. Thus, the volume fractions are slightly different. Experimental data suggest that Al3Ni2 is the main phase in the microstructure, in contrast to the amount of phase obtained by Thermo-Calc in Table 1. The major crystallographic data is summarized in Table 2.

Table 2.

List of phases, volume fraction (mol %), Space Group and the lattice parameters of Al40Cu15Fe10Cr15Fe15Si15 (HEA1), Al65Cu5Cr5Si15Mn5Ti5 (HEA2) and Al60Cu10Fe10Cr5Mn5Ni5Mg5 (HEA3) cast alloys obtained by XRD.

Alloy  Phase  Space Group  Volume fraction  Lattice parameter (Å) 
HEA1Al13Fe4  B2/m (10)  57  a=15.49, b=8.08, c=12.48 
τ1-AlFeSi  P1⃛ (2)  10  a=4.65, b=3.27, c=7.50 
FeSi  P213 (198)  33  a=b=c=4.49 
HEA2Al0.74Mn0.20Si0.06  Pm3⃛ (200)  47  a=b=c=9.71 
Al2Cu  I4/mcm (140)  a=b=6.07, c=4.89 
Al5Si12Ti7  I41/amd (141)  13  a=b=3.57, c=27.15 
Al19Mn4  Pm3⃛ (200)  13  a=b=c=12.68 
HEA3Al3Ni2  P3⃛m1 (164)  77  a=b=4.22, c=5.16 
Al7Cu4Ni  R3⃛m (166)  a=b=4.10, c=39.97 
Mg2Cu6Al5  Pm3⃛ (200)  15  a=b=c=8.31 

The overall bulk composition of the alloys was estimated using EDS on large areas. At least three random measurements were made and the overall values are presented in Table 3. Overall values of Al60Cu10Fe10Cr5Mn5Ni5Mg5 alloy, slightly deviate from the nominal concentration due evaporation losses of Mg during the melting process.

Table 3.

Chemical composition in at. % of the manufactured alloys.

Alloy  Al  Cu  Fe  Cr  Si  Mn  Ti  Ni  Mg 
Al40Cu15Cr15Fe15Si15  41  13  14  16  16  –  –  –  – 
Al65Cu5Cr5Si15Mn5Ti5  66  –  13  –  – 
Al60Cu10Fe10Cr5Mn5Ni5Mg5  60  11  10  –  – 

Fig. 3(a) shows the SEM micrograph of the polished surface of as-cast Al40Cu15Cr15Fe15Si15 alloy. In Fig. 3(b) the marked surface was magnified to identify small region marked as oxides, this region cannot be observed in Fig. 3(a) due to the negligible amount of phase that it represents in the alloy. The main areas in the morphology of the alloy are Region 1 and Region 2 (dark compounds). Surrounded by these regions, it can be observed Region 3 and a small amount of oxides.

Fig. 3.

(a) SEM image of cast Al40Cu15Cr15Fe15Si15 alloy (b) high magnification of marked surface.


In Fig. 4(a) qualitative elemental mapping was conducted by EDS to identify the distribution of elements in the observed regions. The results agree well with Fig. 3 and three areas can be distinguished in the elemental mapping. The main areas in the morphology of the alloy are Region 1, which is rich in Al-Cr and Region 2, rich in Al-Fe. Surrounded by these regions, it can be observed (Al,Cu)-rich area (Region 3) and small amount of oxides. From the EDS pattern in Fig. 4(b), it can be observed that the oxides region is mainly composed of impurities such as O, Mg and Sn.

Fig. 4.

(a) EDS elemental mapping of cast Al40Cu15Cr15Fe15Si15 alloy and (b) EDS pattern of oxides-region.


Fig. 5(a) shows the complex morphology of Al65Cu5Cr5Si15Mn5Ti5 alloy, the microstructure is composed of four different regions. The contrast between regions is relatively high due to their complex compositions, which are composed of at least three elements. In Fig. 5(b), the marked surface was magnified for a better understanding of the complex morphology of the alloy.

Fig. 5.

(a) SEM image of cast Al65Cu5Cr5Si15Mn5Ti5 alloy (b) high magnification of marked surface.


Elemental mapping was conducted by EDS as shown in Fig. 6 to identify the distribution of elements in the observed regions. The microstructure shows a matrix composed of Al-rich area (Region 1) and Al-Cu-rich area (Region 2). The brightest region is marked as Region 3, this region is composed of Si and Ti. Finally, needle-like and irregularly sized Region 4 can be observed not homogeneously distributed throughout the whole alloy.

Fig. 6.

EDS elemental mapping of cast Al65Cu5Cr5Si15Mn5Ti5 alloy.


The SEM image in Fig. 7 of Al60Cu10Fe10Cr5Mn5Ni5Mg5 alloy shows a typical dendritic microstructure, indicating constitutional segregation during the non-equilibrium solidification. In contrast to Thermo-Calc predictions but accordingly with XRD results, only three regions can be distinguished. Fine cracks are also observed in Fig. 7(a).

Fig. 7.

(a) SEM image of cast Al60Cu10Fe10Cr5Mn5Ni5Mg5 alloy (b) high magnification of marked surface.


In Fig. 8 Elemental mapping was conducted by EDS to identify the distribution of elements in the observed regions. The dendrites (Region 1) as well as the interdendritic area (Region 2) consist of a mixture of all the elements in the alloy except Mg. The amount of Ni in the interdendritic region is significantly higher than in the dendritic region. There is compositional segregation inside the interdendritic region of Mg and Cu, marked as Region 3. As can be seen in Fig. 7(a), the main region of the alloy is Region 2. From elemental composition obtained in Fig. 8 and the phase constitution predicted in Table 1, Al3Ni2 phase (Table 2) was correlated to the dendritic region. Moreover, this shows good agreement with the volumetric fraction of phases obtained experimentally in Table 2.

Fig. 8.

EDS elemental mapping of as-cast Al60Cu10Fe10Cr5Mn5Ni5Mg5 alloy.


The microhardness of the fabricated alloys was evaluated on Vickers microhardness tester. The mean microhardness values with the standard deviation are 916±99Hv for Al40Cu15Cr15Fe15Si15, 889±281 Hv for Al65Cu5Cr5Si15Mn5Ti5 and 743±95 for Al60Cu10Fe10Cr5Mn5Ni5Mg5 alloy. The standard deviation of the microhardness in Al65Cu5Cr5Si5Mn5Ti5 is very large due to the complex morphology observed in Fig. 5. Table 4 lists the microhardness and density of manufactured alloys in present work, and previously reported LWHEAs with density below 4.6g/cm3.

Table 4.

Density and microhardness of manufactured alloys in comparison with other published results.

Alloy  ρ (−3Hardness (Hv)  Ref. 
Al40Cu15Cr15Fe15Si15  4.5  916  – 
Al65Cu5Cr5Si15Mn5Ti5  3.7  889  – 
Al60Cu10Fe10Cr5Mn5Ni5Mg5  4.6  743  – 
Al20Li20Mg10Sc20Ti30  2.7  591  [37] 
Al20Be20Fe10Si15Ti35  3.9  911  [38] 
Mg20(MnAlZnCu)80  4.3  431  [33] 
Mg33(MnAlZnCu)77  3.3  310  [33] 
Mg43(MnAlZnCu)67  2.5  250  [33] 
Mg45.6(MnAlZnCu)54.4  2.4  225  [33] 
Mg50(MnAlZnCu)50  2.2  178  [33] 
MgMnAlZnCu (air cooling)  4.3  431  [34] 
MgMnAlZnCu (water cooling)  4.3  449  [34] 
MgMnAlZnCu (salt water cooling)  4.3  467  [34] 
Al40Cu15Mn5Ni5Si20Zn15  4.1  887  [31] 
Al35Cu5Fe5Mn5Si30V10Zr10  4.0  751  [31] 
Al50Ca5Cu5Ni10Si20Ti10  3.3  437  [31] 

To date, the hardness of Al40Cu15Cr15Fe15Si15 alloy is the highest value reported for a LWHEA. In addition, the hardness to density ratio of Al65Cu5Cr5Si15Mn5Ti5 is the highest reported to date. Al40Cu15Cr15Fe15Si15 and Al60Cu10Fe10Cr5Mn5Ni5Mg5 alloys have similar density to pure Ti and Ti-6Al-4V alloys, for which the common hardness values range is from 200 to 369Hv [41]. But the hardness of Al40Cu15Cr15Fe15Si15 and Al60Cu10Fe10Cr5Mn5Ni5Mg5 is considerably higher. According to the Tabor relation [42], the Vickers hardness divided by 3 should approximate the yield strength. Values estimated by this way are 2994MPa for Al40Cu15Cr15Fe15Si15, 2916MPa for Al65Cu5Cr5Si15Mn5Ti5 and 2429MPa for Al60Cu10Fe10Cr5Mn5Ni5Mg5 alloy. These values are higher than tungsten high speed tool steels and to those of traditional structural materials.


In summary, three novel Al40Cu15Cr15Fe15Si15, Al65Cu5Cr5Si15Mn5Ti5 and Al60Cu10Fe10Cr5Mn5Ni5Mg5 LWHEAs were designed by Thermo-Calc in conjunction with TCAL5 database and produced by large scale vacuum die casting. In addition, low density and high hardness from 743 to 916Hv was reported for manufactured alloys.

The LWHEAs have been fabricated by large-scale vacuum die casting. Our results suggested that affordable LWHEAs with high hardness can be adapted to large-scale industrial production.

There are some discrepancies between the experimental results and Thermo-Calc calculations. CALPHAD thermodynamic modeling successfully predicted the constituent phases, which are consistent with the experimental results. However, more phases are predicted by Thermo-Calc in Al40Cu15Cr15Fe15Si15 and Al60Cu10Fe10Cr5Mn5Ni5 alloys at RT than those observed in the samples. This suggests that despite having a slow cooling rate of solidification, total equilibrium state is not achieved in the manufacturing of the alloys. In general, this database has proven to be a good method for designing Al-based HEAs.

The high microhardness of the manufactured alloys is due to the presence of complex precipitates containing multiple elements on their respective sublattices as strengtheners.

New LWHEAs can provide a combination of low density and microstructures that could increase wear, strength, and performance at high temperatures of traditional light-weight alloys. The hardness of Al40Cu15Cr15Fe15Si15 and hardness to density ratio of Al65Cu5Cr5Si15Mn5Ti5 are the highest of all LWHEAs previously reported. Therefore, we estimate that these newly designed LWHEAs have wide application prospects and can be of interest for future research. In addition to the applications mentioned above, we propose these alloys to be used as casing or structural materials of laptops or smartphones. For this, low density materials with high strength and especially high hardness are required to avoid scratches and protect the electronics.

Conflicts of interest

The authors declare no conflict of interest.


This work has been partially funded by the Basque government through the project Elkartek: KK-2017/00007.

J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, et al.
Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes.
Adv Eng Mater, 6 (2004), pp. 299-303
B. Cantor, I.T.H. Chang, P. Knight, A.J.B. Vincent.
Microstructural development in equiatomic multicomponent alloys.
Mater Sci Eng A, 375–377 (2004), pp. 213-218
Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, et al.
Microstructures and properties of high-entropy alloys.
K.K. Alaneme, M.O. Bodunrin, S.R. Oke.
Processing, alloy composition and phase transition effect on the mechanical and corrosion properties of high entropy alloys: a review.
J Mater Res Technol, 5 (2015), pp. 384-393
Y. Zhou, D. Zhou, X. Jin, L. Zhang, X. Du, B. Li.
Design of non-equiatomic medium-entropy alloys.
D. Raabe, C.C. Tasan, H. Springer, M. Bausch.
From high-entropy alloys to high-entropy steels.
Steel Res Int, 86 (2015), pp. 1127-1138
H. Zhang, H. Tang, W.H. Li, J.L. Wu, X.C. Zhong, G. Chen, et al.
Novel high-entropy and medium-entropy stainless steels with enhanced mechanical and anti-corrosion properties.
Mater Sci Technol (United Kingdom), (2017), pp. 1-8
K.G. Pradeep, C.C. Tasan, M.J. Yao, Y. Deng, H. Springer, D. Raabe.
Non-equiatomic high entropy alloys: approach towards rapid alloy screening and property-oriented design.
Mater Sci Eng A, 648 (2015), pp. 183-192
N.D. Stepanov, D.G. Shaysultanov, M.A. Tikhonovsky, G.A. Salishchev.
Tensile properties of the Cr-Fe-Ni-Mn non-equiatomic multicomponent alloys with different Cr contents.
Mater Des, 87 (2015), pp. 60-65
Z. Li, K.G. Pradeep, Y. Deng, D. Raabe, C.C. Tasan.
Metastable high-entropy dual-phase alloys overcome the strength-ductility trade-off.
Nature, 534 (2016), pp. 227-230
S. Gorsse, D.B. Miracle, O.N. Senkov.
Mapping the world of complex concentrated alloys.
Acta Mater, 135 (2017), pp. 177-187
D.B. Miracle, O.N. Senkov.
A critical review of high entropy alloys and related concepts.
W. Zhang, P.K. Liaw, Y. Zhang.
Science and technology in high-entropy alloys.
Sci China Mater, 61 (2018), pp. 2-22
B. Cantor.
Multicomponent and high entropy alloys.
Entropy, 16 (2014), pp. 4749-4768
X. Yang, Y. Zhang.
Prediction of high-entropy stabilized solid-solution in multi-component alloys.
Mater Chem Phys, 132 (2012), pp. 233-238
Y. Zhang, Y.J. Zhou, J.P. Lin, G.L. Chen, P.K. Liaw.
Solid-solution phase formation rules for multi-component alloys.
Adv Eng Mater, 10 (2008), pp. 534-538
S. Guo.
Phase selection rules for cast high entropy alloys: an overview.
Mater Sci Technol, 31 (2015), pp. 1223-1230
S. Guo, C. Ng, J. Lu, C.T. Liu.
Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys.
J Appl Phys, (2011), pp. 109
M.C. Gao, C. Zhang, P. Gao, F. Zhang, L.Z. Ouyang, M. Widom, et al.
Thermodynamics of concentrated solid solution alloys.
Curr Opin Solid State Mater Sci, 21 (2017), pp. 238-251
F. Tian, L.K. Varga, N. Chen, L. Delczeg, L. Vitos.
Ab initio investigation of high-entropy alloys of 3d elements.
Phys Rev B – Condens Matter Mater Phys, (2013), pp. 87
Z. Liu, Y. Lei, C. Gray, G. Wang.
Examination of solid-solution phase formation rules for high entropy alloys from atomistic Monte Carlo simulations.
JOM, 67 (2015), pp. 2364-2374
M.C. Gao, P.K. Liaw, J.-W. Yeh, Y. Zhang.
High-entropy alloys: fundamentals and applications, (2016),
F. Zhang, C. Zhang, S.L. Chen, J. Zhu, W.S. Cao, U.R. Kattner.
An understanding of high entropy alloys from phase diagram calculations.
Calphad Comput Coupling Phase Diagr Thermochem, 45 (2014), pp. 1-10
H.L. Chen, H. Mao, Q. Chen.
Database development and Calphad calculations for high entropy alloys: challenges, strategies, and tips.
Mater Chem Phys, 210 (2018), pp. 279-290
H. Mao, H.L. Chen, Q. Chen.
TCHEA1: a thermodynamic database not limited for “High Entropy” alloys.
J Phase Equilibria Diffus, 38 (2017), pp. 353-368
C. Zhang, F. Zhang, H. Diao, M.C. Gao, Z. Tang, J.D. Poplawsky, et al.
Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys.
Mater Des, 109 (2016), pp. 425-433
R. Feng, M. Gao, C. Lee, M. Mathes, T. Zuo, S. Chen, et al.
Design of light-weight high-entropy alloys.
Entropy, 18 (2016), pp. 333
W. Sun, X. Huang, A.A. Luo.
Phase formations in low density high entropy alloys.
Calphad Comput Coupling Phase Diagr Thermochem, 56 (2017), pp. 19-28
J.M. Sanchez, I. Vicario, J. Albizuri, T. Guraya, N. Koval, J. Garcia.
Compound formation and microstructure of As-cast high entropy aluminiums.
Metals (Basel), 8 (2018), pp. 167
R. Feng, M.C. Gao, C. Zhang, W. Guo, J.D. Poplawsky, F. Zhang, et al.
Phase stability and transformation in a light-weight high-entropy alloy.
Acta Mater, 146 (2018), pp. 280-293
R. Li, J. Gao, K. Fa.
Study to microstructure and mechanical properties of Mg containing high entropy alloys.
Mater Sci Forum, 650 (2010), pp. 265-271
R. Li, J.-C. Gao, K. Fan.
Microstructure and mechanical properties of MgMnAlZnCu high entropy alloy cooling in three conditions.
Mater Sci Forum, 686 (2011), pp. 235-241
X. Yang, S.Y. Chen, J.D. Cotton, Y. Zhang.
Phase stability of low-density, multiprincipal component alloys containing aluminium, magnesium, and lithium.
JOM, 66 (2014), pp. 2009-2020
K.M. Youssef, A.J. Zaddach, C. Niu, D.L. Irving, C.C. Koch.
A novel low-density, high-hardness, high-entropy alloy with close-packed single-phase nanocrystalline structures.
Mater Res Lett, 3 (2014), pp. 95-99
K. Tseng, Y. Yang, C. Juan, T. Chin, C. Tsai, J. Yeh.
A light-weight high-entropy alloy Al20Be20Fe10Si15Ti35.
Sci China Technol Sci, 841 (2017), pp. 18-23
A. Kumar, M. Gupta.
An insight into evolution of light weight high entropy alloys: a review.
Metals (Basel), 6 (2016), pp. 199
J.O. Andersson, T. Helander, L. Höglund, P. Shi, B. Sundman.
Thermo-Calc & DICTRA, computational tools for materials science.
Calphad Comput Coupling Phase Diagr Thermochem, 26 (2002), pp. 273-312
S.S. Da Rocha, G.L. Adabo, G.E.P. Henriques, M.A.D.A. Nóbilo.
Vickers hardness of cast commercially pure titanium and Ti-6Al-4V alloy submitted to heat treatments.
Braz Dent J, 17 (2006), pp. 126-129
D. Tabor.
The physical meaning of indentation and scratch hardness.
Br J Appl Phys, 7 (1956), pp. 159-166
Copyright © 2018. Brazilian Metallurgical, Materials and Mining Association
Journal of Materials Research and Technology

Subscribe to our newsletter

Article options
Cookies policy
To improve our services and products, we use cookies (own or third parties authorized) to show advertising related to client preferences through the analyses of navigation customer behavior. Continuing navigation will be considered as acceptance of this use. You can change the settings or obtain more information by clicking here.