Journal Information
Download PDF
More article options
Original Article
DOI: 10.1016/j.jmrt.2018.10.009
Open Access
Effect of titanium (IV) isopropoxide molarity on the crystallinity and photocatalytic activity of titanium dioxide thin film deposited via green sol–gel route
Shuhadah A. Yazida, Zulkifli Mohd Roslia,
Corresponding author

Corresponding author.
, Jariah Mohamad Juoib
a Fakulti Teknologi Kejuruteraan Mekanikal dan Pembuatan, Universiti Teknikal Malaysia Melaka, Hang Tuah Jaya, 76100 Durian Tunggal, Melaka, Malaysia
b Fakulti Kejuruteraan Pembuatan, Universiti Teknikal Malaysia Melaka, Hang Tuah Jaya, 76100 Durian Tunggal, Melaka, Malaysia
This item has received

Under a Creative Commons license
Received 18 April 2018, Accepted 19 October 2018
Article information
Full Text
Download PDF
Figures (4)
Show moreShow less
Tables (1)
Table 1. Varied molarity of TTiP prepared by different ratio of DI and TTiP volume.

In this paper, the effect of titanium (IV) isopropoxide TTIP molarity on the crystallinity and TiO2 thin film properties deposited via green sol–gel route was reported. The green sol–gel route is a pioneering approach for eco-friendly coating where solvent is not utilized in the sol formulation. This is in contrast to the common TiO2 sol formulation where solvent is used despite the long term harmful the environment. TiO2 solution with different TTIP molarity of 0.2M, 0.3M, 0.4M and 0.5M were utilized during coating deposition. Deposition were conducted for ten times using dip coating and treated at 500°C (1-h). The crystalline phases and phase content were characterized using X-ray diffraction (XRD) and reference intensity ratio (RIR) equation. Crystallites size was obtained by Scherrer's equation while coating morphologies was analyzed using scanning electron microscope (SEM). The photocatalytic activity was conducted by the degradation of methylene blue (MB) towards UV-light and visible light. At higher TTIP molarity (0.5M), higher crystallinity of mixed anatase (∼17nm) and rutile (∼29nm) phases were obtained along with homogeneous coating (cracking and visible pore). Also, higher MB degradation were obtained at UV-light (95%) and visible-light (86%) irradiation. In conclusion, higher TTIP molarity produced TiO2 film with higher crystallinity, small crystallite size, cracking morphology thus contribute good performance in photocatalytic activity. Findings in this work shown that TiO2 thin film deposition is possible conducted without the use of solvent through optimized formulation of only precursor, acid and water. This is beneficial for the environment sustainability.

Sol–gel dipping
Titanium dioxide
Titanium (IV) isopropoxide
Solvent free
Photocatalytic activity
Green route
Full Text

Water crisis or water pollution have become a most frightening threat to health and environment. Nowadays, increased in water contaminant and colouring in residual waters from industries have been reported [1–3]. Many approaches have been used to eliminate the contaminant and colourants in water like adsorption, flocculation, ozonation and photocatalysis [4]. Photocatalysis promising an efficient and economic method to decompose water contaminant by transform them to benign substances [5].

Introducing titanium dioxide (TiO2) as a photocatalyst, befit fascinated attention due to non-toxicity, low cost, simple synthesis, high catalytic activity and high photo-thermal stability [6–8]. Crystallinity, morphology, crystallite size and surface area of the TiO2 thin film have a substantial influenced in determining the photocatalytic performance [9,10]. For example, high crystallinity of TiO2 polymorphs and small crystallite size with large surface area exhibit good photocatalytic [11]. Lorena [12] claimed that, rapid degradation of methyl orange with the fastest degradation rate obtained at the cracking surface deposited with glass substrate. The cracking structure is expected to reduce the surface area exposed to light and photocatalytic activity [13]. It is also reported that the film consists of anatase crystal with small size of ∼19nm [12].

TiO2 exist with three different polymorphs: anatase, rutile and brookite. These three polymorphs promise a photocatalytic reaction based on its properties. Hanoar [14] reported that mixed TiO2 polymorphs give a good sign in photodegradation of methylene blue compared to single polymorphs. Similar finding is affirmed by Fischer [15], where anatase mixed rutile reduced the photo-generated electrons holes and increased light absorption. A mixture of rutile and brookite as well as anatase and brookite also reported to generate fast degradation rate in organic molecules [14–16]. About 70:30 phases content of anatase to rutile, 91:9 phases content of anatase to brookite and 61:27:12 phase content of anatase to rutile to brookite had generated high photocatalytic performance by >39% degradation of methylene blue at 1-h irradiation by UV-light [15]. Few researchers had also reported that 70:30 content ratio of anatase to rutile exhibit ≥65% of photodegradation above 1-h irradiation at UV-light [9,10], while pure brookite was reported exhibit 92% degradation of methylene blue under 4-h irradiation at visible light [6]. Thus, it can be observed that all three polymorphs do act as a reaction agent however the photodegradation activity is dependent on the TiO2 phase's content.

TiO2 thin film deposited by sol–gel dipping is the most conventional method that offers low temperature processing, provides high surface homogeneity, easy coating in large surface area and low cost [3]. Manasi [13] had found that the TiO2 nanoparticles prepared via sol–gel route is highly crystalline and have smaller crystallite size as compared to the one prepared by hydrothermal method. In sol gel, precursor, solvent, water and catalyst are the known basic parameters which can control the TiO2 properties for photocatalytic activity such as phase content, phase transfer kinetics, particle size distribution, surface area, morphology, and crystallinity of the TiO2 thin film. Precursor were used to derive the TiO2 polymorphs and its crystallinity reported by Hafizah [11]. There are many types of precursor that have been used such as titanium (IV) isopropoxide (TTIP), titanium tetrachloride, titanium tetrabutoxide and titanium alkoxides. TTIP promising a good precursor in producing stable solution at low hydrolysis ratio [17]. In addition, solvent [18] catalyst [7] and water [14] are also functioning in hydrolysis and influencing the condensation rate in forming a stable TiO2 solution.

Solvent have been reported to slow down the rate of hydrolysis and condensation due to the single phase deposited and low specific surface area of the produced TiO2. Ethanol promotes anatase crystalline at low temperature (∼350°C and 400°C) compare to isopropyl alcohol and 2-ethoxcyethanol. It is also favours the growth of rutile with lower growth rate compare to methanol. 100% of ethanol produced anatase crystalline while 100% of methanol produced 100% of rutile [19]. However, it is also reported that the used of ethanol can hinder the anatase formation and produce larger nucleus formation and critical particle size of anatase and form amorphous structure. Using ethanol and methanol exhibit >80% methylene blue degradation at 3-h irradiation in pure anatase due to UV light [8]. Nevertheless, it should be noted that organic solvents are volatile organic compounds (VOCs) that can harmful the environment. Based on Babu and Redy [20], solvents from different chemical groups can differ markedly in their characteristics and show varied physiological and toxilogical properties, which all too often are neglected in daily life. For example; Plotka [18] stated that organic solvents act as modifier (co-solvent) for carbon dioxide extraction to achieve greenness but due to the high percentage of solvent used to increase the solubility of the target compound had lead towards high toxicity. This is unhealthy and harmful to human and environment. Consequently, it is vital to practice green chemistry approach in work related to TiO2 deposition. In this pioneering work, first green chemistry principle which is prevention (it is to better to prevent waste than to treat or clean up waste after it has been created) is applied where the use of solvent is avoided during the sol formulation. This is in contrast to the common formulation sol utilized in most work related to TiO2 thin film deposition where solvent is almost a compulsory ingredient.

At present, few researchers had reported an alternative method in replacing solvent by utilizing additives, dopants and stabilizers in favours to growth mixed polymorphs with different band gap for photocatalytic performance in UV-light and visible light [4,21,22]. Yu [22] reported that TiO2 doped with Au will exhibit strong absorption of the visible light and thus increased photocatalytic performance under the visible light illumination. 95% and 97% of Rhodamine B was degrade at UV and visible light with the Au decoration. Next, stabilizer was used to replace the solvents on promoting the anatase and rutile phase precipitation on TiO2 coating films [22]. It can be concluded that, phase content and photocatalytic performance can be acquired without the use of solvent, but critical or complex formulation was derived.

Therefore, 5th principle of green chemistry (waste prevention, design of safer, non-persistent, biodegradable chemicals and inherently safer chemistry for accident prevention) was introduced in this research to minimize the solvent utilization during TiO2 coating [18]. Deposited TiO2 thin film with solvent free (without solvent) would be ideal to green coating technology. Moreover, this work employs simple formulation in developing less chemical consumption based on this principle. Basic parameters such as precursors, catalyst and water are required to produce green TiO2 thin film. In the basic parameters, concentration of precursors paid a critical effect in TiO2 properties. Concentration of precursor helps in determining TiO2 structure, crystallite size and crystallinity that can have enhanced photocatalytic performance. Hafizah [11] reported that crystallite size depends on the concentration of TTIP precursor. Decreased in TTIP concentration will decrease the crystallite size. In contrast, Fagnern [3] claimed that increased the TTIP concentration from 2mol to 3mol had increase the anatase content with an average crystallite size of ∼20nm. These resulted producing high photodegradation on Reactive Blue19 solution at 88% after 5-h irradiation by UV-light [3]. Moreover, TTIP concentration also influenced the surface morphology of the TiO2 thin film. 1mol of TTIP produced no surface cracking while 2mol and 3mol of TTIP shown cracking due to internal stress and film shrinkage [3]. It is found that most of the works on the effect of TTIP concentrations were conducted during deposition of TiO2 thin film with solvent in the formulation.

Therefore, in this work, effect of TTIP molarity on the crystallinity and photocatalytic activity of TiO2 thin film deposited without solvent were studied. This is in line with an effort to attain green TiO2 coating for photocatalytic activity via UV-light and visible light applications.

2Methodology2.1TiO2 thin film preparation

TiO2 solutions were prepared by sol–gel method. Titanium (IV) isopropoxide (TTIP) (Sigma–Aldrich Co.), hydrochloric acid (37% HCl) and deionized water (DI) are used as titanium precursor, catalyst and hydrolysis medium respectively. In general, TiO2 solutions were prepared by dissolving TTIP to DI water under constant stirring for 30min at 25°C followed by 0.4ml of HCl. The solutions were keep on continuous stirring for 3h before they kept in room condition for 48h ageing process. Varied molarity of TTIP was prepared by using different ratio of deionized water to TTIP volume shown in Table 1. Next, TiO2 solution with different TTIP molarity of 0.2M, 0.3M, 0.4M and 0.5M are deposited on the glass slides, 25.4mm×10mm×10mm in size to examine influence of TTIP molarity on the crystallinity, crystallite size, morphology and photocatalytic activity of TiO2 thin film.

Table 1.

Varied molarity of TTiP prepared by different ratio of DI and TTiP volume.

Sols  Volume (ml)Molarity of TTiP (M) 
  DI  TTiP  HCl   
T2  64  0.4  0.2 
T3  64  0.4  0.3 
T4  32  0.4  0.4 
T5  32  0.4  0.5 

The dip coating procedure was carried out by using a mechanical dip coater machine employing 30mm/min dipping speed and 5s dwelling time. The coated substrates were then allowed to dry for 24h followed by oven dry at 110°C for 30min. The coating procedures are repeated for ten times to produce TiO2 thin film coating. Heat treatment process was carried out at 500°C for 1h with a heating rate of 5°C/min.

2.2Characterization of TiO2 thin film

Analysis of the crystalline structures was performed by XRD diffractometer (PANalytical X’PERT PRO MPD Model PW 3060/60) with wavelength of Cu K∝ (∼1.54060Å at 30mA and 40kV) radiation in 2θ range from 10° to 80°. Further analysis on crystalline structures was affirmed by Raman Spectrometer (UniRAM-3500) with 532nm to match the resulted obtained from XRD diffractometer. Next, phase content of TiO2 thin film were calculated from the integrated intensities of the anatase (101), rutile (110) and brookite (121) diffraction peaks by reference intensity ratio (RIR) method shown in Eqs. (1)–(3):

where WR, WA, WB, AR, AA and AB were representing the mass fraction and integrated intensity for the rutile, anatase and brookite respectively. The average of crystallites size, L were calculated at strongest XRD line [(101) at 25°], [(110) at 27°)] and [(121 at 30°)] by Scherrer's equation (4):
where L is the mean size of the crystalline with K denoted as a constant with a value of 0.94 and λ is the wavelength of X-rays. θ is the Bragg angle while β is the line broadening at half the maximum intensity (FWHM). Morphologies of the TiO2 thin film structured was studied by scanning electron microscopic (SEM) Carl Zeiss EVO 50 at an accelerating voltage of 10kV.

2.3Photocatalytic activity

Photocatalytic activity was evaluated by degrading the methylene blue (MB) solutions under UV-light (Philips, 58W) and visible light (OSRAM, 200W) conditions at 5-h irradiation. The degradation of MB obtained by residual absorbance was analyzed by SHIMADZU UV-1700 UV-Vis spectrometer at 664nm. The decrease in absorbance indicate the degradation of MB. The percentage of MB degradation was calculated by Eq. (5).

where Co represents the initial concentration after the equilibrium adsorption, C represents the reaction concentration of MB solution, Ao represents the initial absorbance, and A represents the changed absorbance of the MB solution.

3Results and discussion3.1Crystallinity of TiO2 thin film

Fig. 1 shows the XRD pattern and Raman spectrum of TiO2 thin film with different TTIP molarity heat treated at 500°C. Increased in TTIP molarity had increased the crystallinity of TiO2 phases defined by the number of crystalline peaks shown in Fig. 1(a). For 0.2M, mixed anatase and rutile are observed where anatase are detected at peak 25°, 48°, 54° and rutile at peak 27°. The present of rutile is confirmed by Raman spectrum detected at 448cm−1 shown in Fig. 1(b). For 0.3M, mixed of three polymorphs are observed which are anatase, rutile and brookite. Brookite presence is identified at peak 31°. This is confirmed by Raman spectrum detected at 248cm−1 and 321cm−1. For 0.4M and 0.5M, mixed anatase and rutile (without brookite) are observed. Where anatase were seen at peak 25°, 48°, 54°, 56°, 59°, 63°, 68°, 73° while rutile was seen at 27°, 35°, 37°, 41°, and 44°. Number of crystalline peaks identified represent the crystallinity of TiO2 thin film [11]. Hafizah [11] claimed that, increased of TTIP concentration would increase the viscosity of the TiO2 solution hence produced more crystalline peak of the TiO2 thin film. This is also in agreement with Fagnern [3] findings where increased in the concentration of TTIP precursors by 1mol until 3mol had increased the crystallinity of anatase. Thus, it is believed that higher of TTIP molarity produced more crystalline peak during deposition of TiO2 without solvent.

Fig. 1.

XRD pattern and Raman spectrum of TiO2 thin film with different TTiP molarity heat treated at 500°C (A: anatase, R: rutile, B: brookite).

Fig. 2(a) shows the phases content of anatase, rutile and brookite calculated from XRD lines located at peak 25° for anatase, 27° for rutile and 31° for brookite. For 0.2M, 76:24 percent of the phases content was observed and identified as anatase and rutile. For 0.3M, 53:39:8 percent of the phases content was observed and assigned as anatase, rutile and brookite. Decreased in anatase content was caused by transformation of rutile to brookite phase as had been also reported by Han [14]. For 0.4M, 59:41 percent of the phases content was observed and identified as anatase and rutile. For 0.5M, 63:37 percent of the phases content was observed and identified as anatase and rutile. Increased in anatase content from 0.4M to 0.5M of TTIP was due to higher anatase crystallinity observed at XRD pattern. This agrees with Wong [23] findings where increased in the concentration of precursors had increased the anatase crystallinity with reduced rutile phases content.

Fig. 2.

Phases content and crystallite size of TiO2 thin film with different TTiP molarity.

Fig. 2(b) shows the crystallite size of TiO2 thin film with different TTIP molarity located at peak 25° for anatase, 27°for rutile and 31° for brookite. For 0.2M, crystallite size of anatase and rutile were identified at 21nm and 34nm. The crystallite size of anatase and rutile decreased in size (∼14nm for anatase and ∼11nm for rutile) at 0.3M due to the presence of brookite). At higher molarity at 0.5M crystallite size of anatase and rutile reduced to ∼17nm and ∼29nm. This observation agrees with Hafizah and Fagnern findings where increased in precursor molarity had decreased the TiO2 crystallite size.

3.2Photocatalytic activity

Fig. 3 shows the percentage of MB degradation for UV-light spectrum and SEM images of TiO2 thin film at different TTIP molarity. At 0.2M, 81% of MB solution was degraded, while at higher molarity of TTIP 0.4M and 0.5M, the degradation of MB solution increased to above 90% (Fig. 3(a)). 0.5M of TTIP shows the highest MB degradation of 97%. The higher degradation of MB solutions is due to the higher crystallinity presence at higher TTIP molarity. Moreover, it is also due to the small crystallite size obtained during the TiO2 deposition (∼17nm for anatase and ∼29nm for rutile). The surface morphology of the TiO2 thin film revealed that at 0.2M, the surface of TiO2 thin film shown cracking with no pores observed (Fig. 3(b)). In contrast, 0.3M less cracking was identified. At higher molarity of TTIP (0.4M and 0.5M), severe cracking and visible pores were observed. Large pore produced was due to internal stress exerted caused by high viscosity of TTIP content [11]. It has been suggested by Lorena [12] that, rapid degradation of methyl orange obtained when high cracking and large pore deposited on the glass substrate due small surface area exerted lead to high absorption during photocatalytic activity. Thus, this agrees with microstructure observed and high MB degradation at 0.5M by UV-light.

Fig. 3.

Percentage of MB degradation for UV-light spectrum and SEM images of TiO2 thin film at different TTiP molarity.

Fig. 4 shows percentage of MB degradation for visible light spectrum of TiO2 thin film at 0.3M and 0.5M TTIP. These two formulations were selected for visible light analysis due to the presence of brookite at 0.3M and highest MB degradation obtained at 0.5M during UV-light irradiation. For 0.3M, 65% of MB solution was degraded for visible light while 0.5M show 86% of MB degradation. Higher in MB degradation presented at 0.5M of TTIP molarity was caused by the higher crystallinity peaks obtained during this formulation [14]. Thus, it is shown that TiO2 thin film deposited with higher TTIP molarity using formulation without solvent, dopants or stabilizers had been able to produce good photocatalytic activity in visible light.

Fig. 4.

Percentage of MB degradation for visible light spectrum of TiO2 thin film at 0.3M and 0.5M TTiP.


TiO2 film with different TTIP molarity (without solvent) have been successfully deposited on glass substrate via sol–gel dip-coating technique. The higher TTIP molarity had increased the crystallinity of mixed phases TiO2 (anatase and rutile) produced. Small crystallite size (∼17nm of anatase and 29nm of rutile) and cracking surface of TiO2 thin films were also observed with higher TTIP molarity. For photocatalytic activity, TiO2 thin films with higher TTIP molarity had increased MB degradation ≥97% in UV-light. Further works will be directed on optimizing other process parameter (for example increase in soaking time with 0.3M of TTIP formulation) to achieve high MB degradation (≥95%) in visible light application. In conclusion, this work had also shown that TiO2 thin film deposition is possible to be conducted without the use of solvent through optimized formulation of only precursor, acid and water (despite the common formulation which utilize solvent and less eco-friendly method). This green sol–gel route applies the prevention method of green chemistry principle, thus is beneficial for environment sustainability. Therefore, this green sol–gel route is recommended to be utilized for related work inTiO2 thin film deposition.

Conflicts of interest

The authors declare no conflicts of interest.


The authors would like to thank the financial support given by the Ministry of Higher Education Malaysia and Universiti Teknikal Malaysia Melaka (UTeM) through FRGS/1/2016/TK05/FKP-AMC/F00319 Grant as well as the Sustainable Material for Green Technology (SM4GT) group members of the Advanced Manufacturing Centre (AMC), UTeM.

A. Castro-Beltrán, P.A. Luque, H.E. Garrafa-Gálvez, R.A. Vargas-Ortiz, A. Hurtado-Macías, A. Olivas
Titanium butoxide molar ratio effect in the TiO2 nanoparticles size and methylene blue degradation
Optik, 157 (2018), pp. 890-894
W. Fu, G. Li, Y. Wang, S. Zeng, Z. Yan, J. Wang
Facile formation of mesoporous structured mixed-phase (anatase/rutile) TiO2 with enhanced visible light photocatalytic activity
Chem Commun, 54 (2018), pp. 2-5
N. Fagnern, R. Leotphayakkarat, C. Chawengkijwanich, M.P. Gleeson, N. Koonsaeng, S. Sanguanruang
Effect of titanium-tetraisopropoxide concentration on the photocatalytic efficiency of nanocrystalline thin films TiO2 used for the photodegradation of textile dyes
J Phys Chem Solids, 73 (2012), pp. 1483-1486
R. Khoshnavazi, S. Fereydouni, L. Bahrami
Enhanced photocatalytic activity of nanocomposites of TiO2 doped with Zr, y or Ce polyoxometalates for degradation of methyl orange dye
Water Sci Technol, 73 (2016), pp. 1746-1755
R. Khoshnavazi, H. Sohrabi, L. Bahrami, M. Amiri
Photocatalytic activity inhancement of TiO2 nanoparticles with lanthanide ions and sandwich-type polyoxometalates
J Sol-Gel Sci Technol, 83 (2017), pp. 332-341
D. Komaraiah, P. Madhukar, Y. Vijayakumar, M.V. Ramana Reddy, R. Sayanna
Photocatalytic degradation study of methylene blue by brookite TiO2 thin film under visible light irradiation
Mater Today Proc, 3 (2016), pp. 3770-3778
F. Sayilkan, M. Asilturk, H. Sayilkan, Y. Onal, M. Akarsu, E. Arpac
Characterization of TiO2 synthesized in alcohol by a sol–gel process: the effects of annealing temperature and acid catalyst
Turk J Chem, 29 (2005), pp. 697-706
S. Šegota, L. Ćurković, D. Ljubas, I. Houra, N. Tomašić, V. Svetlica
Synthesis, characterization and photocatalytic properties of sol–gel TiO2 films
Ceram Int, 37 (2011), pp. 1153-1160
M. Alzamani, E. Eghdam
Sol–gel synthesis of TiO2 nanostructured film on SiO2 pre-coated glass with a comparative study of solvent effect on the film properties
J Sol-Gel Sci Technol, (2016),
A. Eshaghi, R. Mozaffarinia, M. Pakshir
Photocatalytic properties of TiO2 sol–gel modified nanocomposite films
Ceram Int, 37 (2011), pp. 327-331
N.N. Hafizah, M.Z. Musa, M.H. Mamat, M. Rusop
Characterization of titanium dioxide nanopowder synthesized by sol gel grinding method
Adv Mater Res, 626 (2013), pp. 425-429
L. Lopez, W.A. Daoud, D. Dutta, B.C. Panther, T.W. Turney
Effect of substrate on surface morphology and photocatalysis of large-scale TiO2 films
Appl Surf Sci, 265 (2013), pp. 162-168
M.M. Karkare
Choice of precursor not affecting the size of anatase TiO2 nanoparticles but affecting morphology under broader view
Int Nano Lett, 4 (2014), pp. 111
D.A.H. Hanaor, I. Chironi, I. Karatchevtsev, G. Triani, C.C. Sorrell
Single and mixed phase TiO2 powders prepared by excess hydrolysis of titanium alkoxide
Adv Appl Ceram, 111 (2012), pp. 149-158
K. Fischer, A. Gawel, D. Rosen, M. Krause, A. Abdul Latif, J. Griebel
Low-temperature synthesis of anatase/rutile/brookite TiO2 nanoparticles on a polymer membrane for photocatalysis
Catalysts, 7 (2017), pp. 209
M. Monai, T. Montini, P. Fornasiero
Brookite: nothing new under the sun?
Catalysts, 7 (2017), pp. 304
M.E. Simonsen, E.G. Søgaard
Sol–gel reactions of titanium alkoxides and water: influence of pH and alkoxy group on cluster formation and properties of the resulting products
J Sol-Gel Sci Technol, 53 (2010), pp. 485-497
J. Płotka-Wasylka, M. Rutkowska, K. Owczarek, M. Tobiszewski, J. Namieśnik
Extraction with environmentally friendly solvents
TrAC Trends Anal Chem, 91 (2017), pp. 12-25
L. Hu, T. Yoko, H. Kozuka, S. Sakka
Effects of solvent on properties of sol–gel-derived TiO2 coating films
Thin Solid Films, 219 (1992), pp. 18-23
N. Sanni Babu, S.M. Reddy
Impact of solvents leading to environmental pollution
J Chem Pharmaceut Sci, 3 (2014), pp. 974-2115
D. Wojcieszak, M. Mazur, D. Kaczmarek, J. Morgiel, G. Zatryb, J. Domaradzki
Influence of Nd dopant amount on microstructure and photoluminescence of TiO2 Nd thin films
Opt Mater, 48 (2015), pp. 172-178
Y. Yu, W. Wen, X.Y. Qian, J.B. Liu, J. Wu
M. UV and visible light photocatalytic activity of Au/TiO2 nanoforests with Anatase/Rutile phase junctions and controlled Au locations
Scient Rep, 7 (2017), pp. 1-13
A. Wong, W.A. Daoud, H. Liang, Y. Shan
The effect of aging and precursor concentration on room-temperature synthesis of nanocrystalline anatase TiO2
Mater Lett, 117 (2014), pp. 82-85
Copyright © 2018. Brazilian Metallurgical, Materials and Mining Association
Journal of Materials Research and Technology

Subscribe to our Newsletter

Article options
Cookies policy
To improve our services and products, we use cookies (own or third parties authorized) to show advertising related to client preferences through the analyses of navigation customer behavior. Continuing navigation will be considered as acceptance of this use. You can change the settings or obtain more information by clicking here.